ganikoza@uludag.edu.tr +90 224 27 55 083 Uludağ Üniversitesi, Fen-Edebiyat Fakültesi, Kimya Bölümü, 16059 Görükle / BURSA, TÜRKİYE
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Website:
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Objective of the Course:
The aim of this course is to gain and teach students Carbocations, Carbens, Azetures, Nitrenes, Free Radicals, Singlet Oxygen and the formation and reaction of them.
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Contribution of the Course to Professional Development
Recognize the intermediate products formed in organic reactions and make comments about the products formed.
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Learning Outcomes:
1
The student will learn the structure, stability, formation and reactions of carbocations;
2
The student will know many named rearrangement reaction involving carbocation formation;
3
The student will learn structure and reactivity of carbenes, synthesis and reaction of carbenes;
4
The student will learn structure of azetures and nitrenes and formation and reactions of them;
5
The student will learn structure of free radicals and reactions of them;
6
The student will learn basic information about obtaining and reactions of singlet oxygen;
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Course Content:
Week
Theoretical
Practical
1
Structure and stability of carbocations
Formation and determination of carbocations
Reactions of carbocations
2
Rearrangement of carbocations: Wagner-Meerwein rearrangement. Classical carbocations
3
Non-classical carbocations
4
Structure and reactivity of carbens
5
Synthesis and reactions of carbens
6
Rearrangement of carbens
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Midterm Exam
8
Structure and formation of azetures and nitrenes
9
Curtius and Schmidth rearrangement
10
Lesson and Hofmann rearrangement
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Cycloaddition reaction of nitrenes
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Structure and stability of free radicals
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Formation and reactions of free radicals
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Production and reactions of singlet oxygens
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Textbooks, References and/or Other Materials:
1) Organic Chemistry, Jonathan Clayden, Nick Greeves, Stuart Warren, Peter Wothers, Oxford Chemistry Primer, 2001. 2) Reaksiyon Mekanizmaları, Metin Balcı, TÜBA, 2012
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Assesment
TERM LEARNING ACTIVITIES
NUMBER
PERCENT
Midterm Exam
1
20
Quiz
0
0
Homeworks, Performances
1
20
Final Exam
1
60
Total
3
100
Contribution of Term (Year) Learning Activities to Success Grade
40
Contribution of Final Exam to Success Grade
60
Total
100
Measurement and Evaluation Techniques Used in the Course
Homeworks and written exams
Information
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ECTS / WORK LOAD TABLE
Activites
NUMBER
TIME [Hour]
Total WorkLoad [Hour]
Theoretical
14
3
42
Practicals/Labs
0
0
0
Self Study and Preparation
14
3
42
Homeworks, Performances
1
8
48
Projects
0
0
0
Field Studies
0
0
0
Midtermexams
1
23
23
Others
0
0
0
Final Exams
1
25
25
Total WorkLoad
180
Total workload/ 30 hr
6
ECTS Credit of the Course
6
26
CONTRIBUTION OF LEARNING OUTCOMES TO PROGRAMME QUALIFICATIONS
